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  • Neutron Scattering Reveals Twinning in Halide Perovskites - Advanced Materials Research
    Perovskite materials: Neutrons show twinning in halide perovskites

    Perovskite materials are a class of compounds with the general formula ABX3, where A and B are cations and X is an anion. These materials have a wide range of applications, including in solar cells, light-emitting diodes, and lasers. Halide perovskites are a subclass of perovskite materials in which the X anion is a halide ion (such as Cl-, Br-, or I-).

    Twinning is a phenomenon that occurs when a crystal grows in two or more orientations that are mirror images of each other. This can happen when the crystal lattice is cubic, tetragonal, or hexagonal. Twinning can affect the properties of a crystal, such as its strength, hardness, and electrical conductivity.

    In a recent study, scientists used neutrons to study twinning in halide perovskites. Neutrons are a type of subatomic particle that does not have an electric charge. This makes them ideal for studying materials because they can penetrate solids without being affected by the electric fields of the atoms.

    The scientists used a technique called neutron diffraction to study the structure of halide perovskites. Neutron diffraction is a technique that uses neutrons to measure the distances between atoms in a crystal. The scientists found that twinning was present in all of the halide perovskites that they studied.

    The presence of twinning in halide perovskites can affect the properties of these materials. For example, twinning can make halide perovskites more brittle and less efficient at converting light into electricity. The scientists believe that understanding the role of twinning in halide perovskites could lead to the development of new materials with improved properties.

    The study was published in the journal Nature Materials.

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