Here's why:
* Alkali metals are highly reactive: They readily lose their single valence electron to form a +1 cation.
* Bonding with other rubidium atoms is unfavorable: Rubidium atoms have a very weak attraction to each other.
* Stability as individual atoms: Rubidium atoms are more stable as individual entities than as bonded molecules.
Therefore, when you encounter rubidium, it's in the form of individual rubidium atoms.