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  • Calculate Empirical Formula: Step-by-Step Guide with Example
    Here's how to determine the empirical formula:

    1. Assume a 100 g Sample

    * This makes the calculations easier. We have 29.6 g of oxygen and 70.4 g of fluorine.

    2. Convert Grams to Moles

    * Divide the mass of each element by its molar mass:

    * Oxygen: 29.6 g / 16.00 g/mol = 1.85 mol

    * Fluorine: 70.4 g / 19.00 g/mol = 3.71 mol

    3. Find the Mole Ratio

    * Divide each number of moles by the smallest number of moles (1.85 mol in this case):

    * Oxygen: 1.85 mol / 1.85 mol = 1

    * Fluorine: 3.71 mol / 1.85 mol = 2

    4. Write the Empirical Formula

    * The mole ratio tells us the simplest whole number ratio of atoms in the compound. The empirical formula is OF₂.

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