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  • Boron Oxidation State in Peroxoborate Ion [B(O2)2(OH)2]⁻: A Detailed Explanation
    The peroxoborate ion has the formula [B(O2)2(OH)2]⁻. Here's how to determine the oxidation state of boron:

    * Oxygen: Oxygen usually has an oxidation state of -2, except in peroxides (like O2²⁻) where it has an oxidation state of -1.

    * Hydrogen: Hydrogen usually has an oxidation state of +1.

    * Overall Charge: The peroxoborate ion has a charge of -1.

    Let's break down the oxidation states:

    * Two peroxide groups (O2²⁻): Each peroxide group has two oxygen atoms with an oxidation state of -1, giving a total of -2 per peroxide group. Since there are two peroxide groups, the total contribution from peroxide oxygen is -4.

    * Two hydroxide groups (OH⁻): Each hydroxide group has one oxygen atom with an oxidation state of -2 and one hydrogen atom with an oxidation state of +1. This gives a net oxidation state of -1 per hydroxide group, and a total of -2 for both.

    Now, let's represent the oxidation state of boron as 'x':

    x + (-4) + (-2) = -1

    Solving for x:

    x = -1 + 4 + 2 = +5

    Therefore, the oxidation state of boron in the peroxoborate ion is +5.

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