Rules to Remember
* Oxygen: Oxygen usually has an oxidation number of -2, except in peroxides (where it's -1) and when bonded to fluorine.
* Overall Charge: The sum of oxidation numbers in a polyatomic ion must equal the charge of the ion.
Calculation
1. Oxygen's contribution: There are three oxygen atoms, each with an oxidation number of -2, giving a total of -6.
2. Overall charge: The bromate ion has a charge of -1.
3. Bromine's oxidation number: To balance the charges, the oxidation number of bromine (Br) must be +5.
Therefore, the oxidation number of Br in BrO₃⁻ is +5.