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  • Calculating Molarity of n-Butyllithium Solutions: A Step-by-Step Guide
    Here's how to calculate the molarity of a 23% n-butyllithium solution in hexane:

    1. Understand the Solution Concentration

    * 23% n-butyllithium means that 23 grams of n-butyllithium are present in 100 grams of solution.

    2. Calculate the Mass of Hexane

    * Since the solution is 23% n-butyllithium, the remaining 77% is hexane.

    * Mass of hexane = (77/100) * 100 grams = 77 grams

    3. Calculate the Moles of n-butyllithium

    * Molar mass of n-butyllithium (C4H9Li) = 64.06 g/mol

    * Moles of n-butyllithium = (23 grams) / (64.06 g/mol) = 0.359 moles

    4. Calculate the Volume of the Solution

    * We need to assume a density for the solution to convert mass to volume. Since we don't have that information, we'll assume the density is close to that of hexane (~0.66 g/mL).

    * Volume of solution = (100 grams) / (0.66 g/mL) = 151.5 mL = 0.1515 L

    5. Calculate the Molarity

    * Molarity (M) = (moles of solute) / (volume of solution in liters)

    * Molarity = (0.359 moles) / (0.1515 L) = 2.37 M

    Important Note: This calculation is an approximation due to the assumption about the density of the solution. The actual molarity might vary slightly depending on the precise density of the 23% n-butyllithium solution in hexane.

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