At low concentrations, silver nitrate completely dissociates into silver ions (Ag+) and nitrate ions (NO3-). The moles of silver ions in solution are therefore equal to the moles of nitrate ions.
However, as the concentration of silver nitrate increases, the solubility of the compound decreases. This means that a smaller proportion of the silver nitrate molecules dissociate into ions. As a result, the moles of silver ions in solution become less than the moles of nitrate ions.
The exact relationship between the moles of silver ions and nitrate ions in solution can be determined using a solubility curve. A solubility curve shows the maximum amount of solute that can be dissolved in a solvent at a given temperature. The solubility of silver nitrate in water at 25°C is approximately 220 g/L. This means that a solution containing more than 220 g of silver nitrate per liter will be saturated, and any excess silver nitrate will precipitate out of solution as a solid.
The solubility curve for silver nitrate also shows that the solubility of the compound increases as the temperature increases. This means that a hot solution of silver nitrate can dissolve more solute than a cold solution.