Here's the breakdown:
* Stars are always there. Stars are giant balls of burning gas that emit their own light. They exist 24/7, day and night.
* The Sun's light blocks out the stars. During the day, the Sun's light is so overwhelming that it drowns out the light from the much fainter stars.
* We can see some stars in the daytime. Under very specific conditions, such as high altitudes, clear skies, and being away from city lights, you might be able to spot a few very bright stars like Sirius during the day.
So, while we primarily see stars at night, they're always there, even during the day, but hidden by the Sun's brightness.