Here's why:
* Millikan's oil-drop experiment allowed him to measure the charge of an electron with remarkable precision.
* Knowing the charge of an electron, scientists could then combine this with the known value of the electron's charge-to-mass ratio (determined by J.J. Thomson earlier), to calculate the electron's mass.
Therefore, while Millikan didn't directly "weigh" an electron, his work was crucial in establishing the electron's mass with a high degree of accuracy.