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  • Chromium Orbital Diagram: Construction & Electronic Configuration (Cr, 24)
    Here's how to construct the orbital diagram for Chromium (Cr), which has an atomic number of 24:

    1. Electronic Configuration:

    * Full configuration: 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d⁵

    * Condensed configuration: [Ar] 4s¹ 3d⁵

    2. Understanding the Aufbau Principle and Hund's Rule:

    * Aufbau Principle: Electrons fill orbitals in order of increasing energy levels.

    * Hund's Rule: Electrons will individually occupy each orbital within a subshell before doubling up in any one orbital.

    3. Orbital Diagram:

    * 4s: This orbital has a single electron, represented as an up arrow (↑).

    * 3d: This subshell has five orbitals (dxy, dyz, dxz, dx²-y², dz²), each capable of holding two electrons. According to Hund's Rule, each of the five 3d orbitals will get one electron before any pairing occurs.

    Orbital Diagram for Cr:

    ```

    ↑ ↑ ↑ ↑ ↑

    _ _ _ _ _

    4s | | | | |

    _ _ _ _ _

    3d | ↑ | ↑ | ↑ | ↑ | ↑ |

    _ _ _ _ _

    ```

    Explanation:

    * Chromium's Exception: You might notice that the expected configuration would be [Ar] 4s² 3d⁴. However, Chromium has a half-filled 3d subshell, which is more stable than having a filled 4s orbital and a partially filled 3d subshell. This is due to the added stability of having a half-filled subshell.

    Let me know if you have any further questions!

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