Here's why:
* States are not points: They are areas with borders that stretch across both latitude and longitude.
* Longitude lines run north-south: The furthest west point in New Hampshire will have a different longitude than the furthest east point.
Instead of a single longitude, New Hampshire's range of longitudes is roughly:
* Westernmost: 71.9° West
* Easternmost: 70.6° West
Let me know if you need any further information!