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  • Sublimation in Chemistry: Definition, Process & Examples
    In chemistry, sublimation refers to the transition of a substance directly from the solid phase to the gaseous phase, without passing through the liquid phase. This process occurs when the solid absorbs enough energy to overcome the intermolecular forces holding it together, allowing the molecules to escape into the gas phase.

    Here's a breakdown:

    * Solid: A substance in its solid state has molecules tightly packed together in a fixed structure.

    * Gas: In a gaseous state, molecules are widely spaced and move freely.

    * Sublimation: The process of skipping the liquid phase entirely, going directly from solid to gas.

    Examples of Sublimation:

    * Dry ice: Solid carbon dioxide (CO2) sublimates at room temperature and pressure, producing a cold, dense gas.

    * Naphthalene: Mothballs are made of naphthalene, which sublimates slowly, releasing a vapor that repels moths.

    * Freeze-drying: This technique uses sublimation to remove water from food, preserving it without damaging its nutrients.

    Factors affecting Sublimation:

    * Temperature: Higher temperatures increase the energy of molecules, making sublimation more likely.

    * Pressure: Lower pressure allows molecules to escape the solid phase more easily, promoting sublimation.

    * Intermolecular forces: Substances with weak intermolecular forces are more likely to sublimate.

    Difference between Sublimation and Evaporation:

    While both involve transitions from a condensed phase to a gas, they differ in the starting phase:

    * Sublimation: Solid → Gas

    * Evaporation: Liquid → Gas

    Let me know if you have any other questions!

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