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  • Bromine and Water Reaction: Disproportionation Explained
    Bromine reacts with water in a disproportionation reaction, meaning that the bromine atoms undergo both oxidation and reduction. This results in the formation of bromine acid (HBr) and hypobromous acid (HOBr):

    Br₂ (l) + H₂O (l) ⇌ HBr (aq) + HOBr (aq)

    Here's a breakdown of what happens:

    * Oxidation: One bromine atom gains an electron to form bromide ion (Br-) in HBr. This is a reduction.

    * Reduction: The other bromine atom loses an electron to form hypobromite ion (OBr-) in HOBr. This is an oxidation.

    Important points:

    * The reaction is reversible, meaning that the equilibrium can shift depending on the conditions.

    * HOBr is a weak acid and a powerful oxidizing agent. It is responsible for the bleaching and disinfecting properties of bromine water.

    * The reaction is favored by the presence of excess water.

    * The color of bromine water changes from orange-brown to pale yellow due to the formation of HOBr.

    Applications:

    This reaction is important in various applications, including:

    * Disinfection: Bromine water is used as a disinfectant in pools and spas.

    * Bleaching: HOBr is a powerful bleaching agent.

    * Organic synthesis: HOBr is used as a reagent in various organic reactions.

    Overall, the reaction between bromine and water is a complex but important process that leads to the formation of several valuable chemical species.

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