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  • Oxygen's Oxidation Number: Understanding the Rule & Exceptions
    The usual oxidation number for oxygen in a compound is -2.

    There are a few exceptions to this rule:

    * In peroxides (like H₂O₂), oxygen has an oxidation number of -1.

    * In superoxides (like KO₂), oxygen has an oxidation number of -1/2.

    * When oxygen is bonded to a more electronegative element (like fluorine in OF₂), it has a positive oxidation number.

    However, in the vast majority of compounds, oxygen will have an oxidation number of -2.

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