Here's why:
* Oxidation numbers represent the hypothetical charge an atom would have if all bonds were ionic.
* In a neutral molecule, the sum of the oxidation numbers of all atoms must equal zero.
* Hydrogen typically has an oxidation number of +1.
* Carbon has a variable oxidation number, but in hydrocarbons, it's typically -3.
Let's calculate the oxidation number of carbon in propane:
* 3 carbon atoms * x (oxidation number of carbon) + 8 hydrogen atoms * (+1) = 0
* 3x + 8 = 0
* 3x = -8
* x = -8/3
Since we can't have fractional oxidation numbers, we can say that the average oxidation number of carbon in propane is -3.
Important Note: While the average oxidation number of carbon in propane is -3, this doesn't mean each carbon atom individually has a -3 oxidation number. The oxidation numbers are assigned based on electronegativity differences, and the bonds in propane have some covalent character.