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  • Acid-Base Reactions: Impact of Acids on Hydroxide Ion Concentration
    When you add an acid to an aqueous solution, the hydroxide ion concentration decreases. Here's why:

    * Acids donate H+ ions: Acids are substances that release hydrogen ions (H+) into solution.

    * Water auto-ionizes: Water molecules can react with each other to form hydronium ions (H3O+) and hydroxide ions (OH-):

    * 2H2O(l) ⇌ H3O+(aq) + OH-(aq)

    * Le Chatelier's Principle: Adding acid (H+) shifts the equilibrium of this reaction to the left, favoring the formation of water molecules and consuming hydroxide ions (OH-).

    In summary:

    * Increasing the hydrogen ion concentration (adding an acid) reduces the hydroxide ion concentration.

    * This is a direct consequence of the auto-ionization of water and Le Chatelier's principle.

    Note: The relationship between hydrogen ion concentration ([H+]) and hydroxide ion concentration ([OH-]) is defined by the ionic product of water (Kw):

    * Kw = [H+][OH-] = 1.0 x 10^-14 at 25°C

    * As [H+] increases, [OH-] must decrease to maintain a constant Kw value.

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