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  • Xenon vs. Chlorine: Calculating Average Molecular Speed at Equilibrium
    Here's how to solve this problem:

    1. Understand the Concepts

    * Average Speed of Gases: The average speed of gas molecules is related to their temperature and molar mass.

    * Root-Mean-Square Speed (vrms): A common way to express the average speed of gas molecules is the root-mean-square speed. The formula is:

    vrms = √(3RT/M)

    where:

    * R is the ideal gas constant (8.314 J/mol·K)

    * T is the temperature in Kelvin

    * M is the molar mass in kg/mol

    2. Set up the Equation

    We want the vrms of xenon (Xe) to be equal to the vrms of chlorine gas (Cl2) at 24°C. Let's call the temperature of xenon Tx:

    √(3R*Tx/MXe) = √(3R*TCl2/MCl2)

    3. Convert Temperatures to Kelvin

    * TCl2 = 24°C + 273.15 = 297.15 K

    4. Determine Molar Masses

    * MXe = 131.29 g/mol = 0.13129 kg/mol

    * MCl2 = 2 * 35.45 g/mol = 70.90 g/mol = 0.07090 kg/mol

    5. Solve for Tx

    Since the '3R' term appears on both sides, it cancels out. We can simplify the equation and solve for Tx:

    √(Tx/MXe) = √(TCl2/MCl2)

    Square both sides:

    Tx/MXe = TCl2/MCl2

    Solve for Tx:

    Tx = TCl2 * (MXe/MCl2)

    6. Calculate Tx

    Tx = 297.15 K * (0.13129 kg/mol / 0.07090 kg/mol)

    Tx ≈ 552.7 K

    7. Convert Back to Celsius

    Tx ≈ 552.7 K - 273.15 = 279.55 °C

    Therefore, xenon atoms will have the same average speed as Cl2 molecules at 24°C when the xenon is at approximately 279.55°C.

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