However, if we're talking about the first four elements discovered and recognized as distinct substances, they are:
1. Fire: While not technically an element in the modern sense, the ancient Greeks considered fire to be one of the four fundamental elements (along with earth, air, and water).
2. Air: Similar to fire, air was considered a fundamental element by the ancient Greeks.
3. Water: Again, considered a fundamental element by the ancient Greeks.
4. Earth: This was also considered a fundamental element by the ancient Greeks.
It's important to note that these "elements" weren't understood as pure substances in the way we understand elements today. They represented broader concepts or states of matter.
The modern understanding of elements began with Robert Boyle in the 17th century, who defined an element as a substance that cannot be broken down into simpler substances by chemical means.
The first elements to be discovered in the modern sense were:
* Sulfur: Known since ancient times, sulfur was recognized as a distinct element by alchemists.
* Mercury: Also known since ancient times, mercury was recognized as a distinct element by alchemists.
* Phosphorus: Discovered in 1669 by Hennig Brand.
* Arsenic: Discovered in the 13th century, though its elemental nature wasn't fully recognized until the 18th century.
Therefore, depending on how you define "elements," the answer could be either the four classical elements (fire, air, water, earth) or the first four elements discovered in the modern sense (sulfur, mercury, phosphorus, arsenic).