Here's why:
* Oxidation: Hydrogen gas (H₂) is oxidized to hydrogen ions (H+)
H₂ → 2H⁺ + 2e⁻
* Reduction: Hydrogen ions (H+) are reduced to hydrogen gas (H₂)
2H⁺ + 2e⁻ → H₂
The SHE's potential is defined as 0.00 V to allow for easy comparison of other half-cells. Any half-cell that has a positive potential relative to the SHE will have a greater tendency to be reduced, while any half-cell with a negative potential will have a greater tendency to be oxidized.