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  • Preparing Sodium Thiosulfate Solution: Why Freshly Boiled Water?
    Sodium thiosulfate solution is prepared in freshly boiled and cooled water because:

    1. To Prevent Bacterial Growth:

    * Sodium thiosulfate is susceptible to bacterial decomposition, especially in the presence of dissolved oxygen.

    * Boiling the water removes dissolved oxygen, creating an anaerobic environment that inhibits bacterial growth.

    * This helps to ensure the solution remains stable and maintains its chemical integrity for a longer duration.

    2. To Remove Dissolved Gases:

    * Boiling water also removes dissolved gases like carbon dioxide (CO₂).

    * CO₂ can react with sodium thiosulfate, leading to the formation of sulfur dioxide (SO₂) and other byproducts, which can affect the solution's purity and stability.

    3. To Remove Impurities:

    * Boiling water helps to remove any impurities or particulate matter that may be present in the water, ensuring a cleaner solution for preparing the sodium thiosulfate.

    4. To Improve Solubility:

    * While not a primary reason, boiling water can slightly increase the solubility of sodium thiosulfate, allowing for a faster and more efficient dissolution process.

    In Summary:

    Preparing sodium thiosulfate solution in freshly boiled and cooled water ensures its stability, purity, and accuracy for various applications, especially in analytical chemistry and photographic processes.

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