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  • Tetraamminecopper(II) Ion ([Cu(NH₃)₄]²⁺) Formation: Reaction & Explanation
    When ammonia reacts with copper(II) hydroxide (Cu(OH)₂), a complex ion called tetraamminecopper(II) ion ([Cu(NH₃)₄]²⁺) is formed.

    Here's the breakdown of the reaction:

    1. Initial Reaction: Ammonia (NH₃) reacts with copper(II) hydroxide (Cu(OH)₂) to form a deep blue solution. This reaction is an equilibrium reaction, meaning it can proceed in both directions.

    Cu(OH)₂(s) + 4NH₃(aq) ⇌ [Cu(NH₃)₄]²⁺(aq) + 2OH⁻(aq)

    2. Formation of the Complex Ion: The copper(II) ion (Cu²⁺) in solution acts as a Lewis acid, accepting electron pairs from the ammonia molecules. Ammonia acts as a Lewis base, donating electron pairs. This results in the formation of the tetraamminecopper(II) complex ion, [Cu(NH₃)₄]²⁺. The four ammonia molecules coordinate to the central copper(II) ion, forming a coordination complex.

    The deep blue color of the solution is characteristic of the tetraamminecopper(II) complex ion.

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