* Elemental Sulfur (S): Oxidation number = 0
* Sulfide ion (S²⁻): Oxidation number = -2
* Sulfur dioxide (SO₂): Oxidation number = +4
* Sulfur trioxide (SO₃): Oxidation number = +6
* Sulfuric acid (H₂SO₄): Oxidation number = +6
* Hydrogen sulfide (H₂S): Oxidation number = -2
To determine the oxidation number of sulfur in a compound:
1. Assign oxidation numbers to other elements in the compound based on their usual oxidation states. (e.g., Oxygen is usually -2, Hydrogen is usually +1)
2. The sum of all oxidation numbers in a neutral compound must equal zero.
3. The sum of all oxidation numbers in a polyatomic ion must equal the charge of the ion.
For example, in sulfur dioxide (SO₂), oxygen has an oxidation number of -2. Since there are two oxygen atoms, the total negative charge is -4. To balance this, the sulfur must have an oxidation number of +4.