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  • Understanding Solubility: Why Cl₂ is Less Soluble than HCl
    Here's the breakdown of why Cl₂ is less soluble in water than HCl:

    * Polarity: HCl is a polar molecule. The hydrogen atom has a partial positive charge (δ+), and the chlorine atom has a partial negative charge (δ-). This polarity allows HCl to form hydrogen bonds with water molecules, which are also polar.

    * Nonpolarity: Cl₂ is a nonpolar molecule. Both chlorine atoms have the same electronegativity, so the electrons are shared equally, resulting in no overall charge separation.

    * Intermolecular Forces: Water is a polar solvent and readily dissolves polar substances. The strong hydrogen bonding between water molecules and HCl molecules facilitates dissolution. Nonpolar substances like Cl₂ cannot form hydrogen bonds with water and are thus less soluble.

    * Hydrogen Bonding: The hydrogen bonding between HCl and water molecules is a strong attractive force that enhances solubility. Cl₂ lacks the ability to participate in hydrogen bonding.

    In Summary:

    The polar nature of HCl allows it to interact strongly with water molecules through hydrogen bonding, making it more soluble than the nonpolar Cl₂.

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