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  • Calculating the Formal Charge of Nitrite (NO₂⁻): A Step-by-Step Guide
    Here's how to determine the formal charge of nitrite (NO₂⁻):

    1. Draw the Lewis Structure

    * Nitrogen (N): 5 valence electrons

    * Oxygen (O): 6 valence electrons each

    * Total valence electrons: 5 + (2 x 6) + 1 (from the negative charge) = 18

    The Lewis structure for nitrite has a double bond between one nitrogen and one oxygen, and a single bond between nitrogen and the other oxygen. The oxygen with the single bond has a negative charge.

    2. Assign Formal Charges

    * Formal Charge = (Valence Electrons) - (Non-bonding Electrons) - (1/2 Bonding Electrons)

    * Nitrogen:

    * Valence Electrons: 5

    * Non-bonding Electrons: 0

    * Bonding Electrons: 8 (4 bonds)

    * Formal Charge = 5 - 0 - (1/2 * 8) = +1

    * Oxygen (double bonded):

    * Valence Electrons: 6

    * Non-bonding Electrons: 4

    * Bonding Electrons: 4

    * Formal Charge = 6 - 4 - (1/2 * 4) = 0

    * Oxygen (single bonded):

    * Valence Electrons: 6

    * Non-bonding Electrons: 6

    * Bonding Electrons: 2

    * Formal Charge = 6 - 6 - (1/2 * 2) = -1

    Conclusion

    The formal charges of nitrite are:

    * Nitrogen: +1

    * Double-bonded Oxygen: 0

    * Single-bonded Oxygen: -1

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