1. Draw the Lewis Structure
* Nitrogen (N): 5 valence electrons
* Oxygen (O): 6 valence electrons each
* Total valence electrons: 5 + (2 x 6) + 1 (from the negative charge) = 18
The Lewis structure for nitrite has a double bond between one nitrogen and one oxygen, and a single bond between nitrogen and the other oxygen. The oxygen with the single bond has a negative charge.
2. Assign Formal Charges
* Formal Charge = (Valence Electrons) - (Non-bonding Electrons) - (1/2 Bonding Electrons)
* Nitrogen:
* Valence Electrons: 5
* Non-bonding Electrons: 0
* Bonding Electrons: 8 (4 bonds)
* Formal Charge = 5 - 0 - (1/2 * 8) = +1
* Oxygen (double bonded):
* Valence Electrons: 6
* Non-bonding Electrons: 4
* Bonding Electrons: 4
* Formal Charge = 6 - 4 - (1/2 * 4) = 0
* Oxygen (single bonded):
* Valence Electrons: 6
* Non-bonding Electrons: 6
* Bonding Electrons: 2
* Formal Charge = 6 - 6 - (1/2 * 2) = -1
Conclusion
The formal charges of nitrite are:
* Nitrogen: +1
* Double-bonded Oxygen: 0
* Single-bonded Oxygen: -1