Here's why:
* Copper (Cu) has two common oxidation states: +1 (cuprous) and +2 (cupric).
* Chlorine (Cl) has an oxidation state of -1.
To balance the charges, copper would need to be in the +3 oxidation state to form CuCl3. However, copper does not readily form compounds in the +3 oxidation state.
The most likely compound you're thinking of is CuCl2, which is copper(II) chloride.