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  • Calculating the Boiling Point Elevation of a Sodium Sulfate Solution
    Here's how to determine the boiling point of a 2.35 m solution of sodium sulfate:

    1. Understand the Concept of Boiling Point Elevation

    * Boiling point elevation is the phenomenon where the boiling point of a solvent is increased when a non-volatile solute is added.

    * The extent of elevation depends on the molality (moles of solute per kilogram of solvent) of the solution and a property called the molal boiling point elevation constant (Kb), which is specific to the solvent.

    2. Determine the Relevant Constants

    * For water:

    * Kb = 0.512 °C/m

    * Normal boiling point = 100 °C

    3. Calculate the Change in Boiling Point (ΔTb)

    * ΔTb = i * Kb * m

    * i: van't Hoff factor (accounts for the number of particles the solute dissociates into)

    * Kb: Molal boiling point elevation constant

    * m: Molality of the solution

    * Sodium sulfate (Na2SO4) dissociates into 3 ions in water:

    * Na2SO4 → 2 Na+ + SO42-

    * Therefore, i = 3

    * Calculate ΔTb:

    * ΔTb = (3) * (0.512 °C/m) * (2.35 m) = 3.62 °C

    4. Calculate the New Boiling Point

    * New boiling point = Normal boiling point + ΔTb

    * New boiling point = 100 °C + 3.62 °C = 103.62 °C

    Therefore, the boiling point of a 2.35 m solution of sodium sulfate is approximately 103.62 °C.

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