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  • Understanding the Point Group of Bent Nitrogen Dioxide (NO2)
    The point group of a bent nitrogen dioxide (NO2) molecule is C2v.

    Here's why:

    * Bent geometry: The molecule has a bent shape due to the presence of a lone pair on the nitrogen atom.

    * Symmetry elements:

    * C2 axis: A rotation by 180 degrees about an axis passing through the nitrogen atom and bisecting the O-N-O angle.

    * Two vertical mirror planes (σv): One plane containing the nitrogen atom and the two oxygen atoms, and another perpendicular to this plane and passing through the nitrogen atom.

    * No horizontal mirror plane (σh): There is no plane of symmetry perpendicular to the C2 axis.

    These symmetry elements define the C2v point group.

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