Here's why:
* pKa is defined for acids. It measures the tendency of an acid to donate a proton (H+).
* Sodium hydroxide is a base, meaning it accepts protons.
* Strong bases have a very weak conjugate acid. The conjugate acid of NaOH is water (H2O), which is a very weak acid.
Therefore, it's not meaningful to talk about the pKa of sodium hydroxide. Instead, we describe its strength as a base.