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  • Why Calcium Chloride Fails as an Ammonia Drying Agent
    Anhydrous calcium chloride (CaCl₂) is not a suitable drying agent for ammonia (NH₃). Here's why:

    * Reaction with Ammonia: Calcium chloride reacts with ammonia to form a complex compound, ammoniacal calcium chloride. This reaction consumes ammonia and prevents it from being dried.

    * Formation of Ammonium Chloride: The reaction between ammonia and calcium chloride can also lead to the formation of ammonium chloride (NH₄Cl), which is a solid and can contaminate the ammonia.

    Suitable Drying Agents for Ammonia:

    Instead of calcium chloride, the following drying agents are commonly used for ammonia:

    * Sodium Metal: Sodium metal is a very effective drying agent for ammonia, but it is highly reactive and requires careful handling.

    * Potassium Hydroxide (KOH): Potassium hydroxide is a strong base and can effectively absorb water from ammonia.

    * Calcium Oxide (CaO): Calcium oxide is a less reactive drying agent than sodium metal or potassium hydroxide, but it is still effective in drying ammonia.

    Note: When choosing a drying agent for ammonia, it is essential to consider its reactivity with ammonia and the desired level of dryness.

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