1. Know the Oxidation State Rules:
* Oxygen usually has an oxidation state of -2 (except in peroxides and superoxides).
* The sum of the oxidation states in a polyatomic ion equals the charge of the ion.
2. Apply the Rules:
* We have three oxygen atoms, each with an oxidation state of -2, for a total of -6.
* The overall charge of the chlorate ion is -1.
* To balance this, the chlorine atom must have an oxidation state of +5.
3. Conclusion:
The oxidation state of chlorine in the chlorate ion (ClO₃⁻) is +5.