1. Find the empirical formula:
* Assume a 100 g sample: This makes the percentages directly into grams.
* Convert grams to moles:
* Moles of Boron (B): 78.14 g / 10.81 g/mol (molar mass of B) = 7.23 mol
* Moles of Hydrogen (H): 21.86 g / 1.01 g/mol (molar mass of H) = 21.64 mol
* Find the simplest whole-number ratio: Divide both mole values by the smaller one (7.23 mol):
* B: 7.23 mol / 7.23 mol = 1
* H: 21.64 mol / 7.23 mol ≈ 3
* Empirical formula: BH₃
2. Determine the molar mass:
* Use the ideal gas law (PV = nRT):
* P = 1.12 atm
* V = 74.3 mL = 0.0743 L
* R = 0.0821 L⋅atm/(mol⋅K)
* T = 27°C + 273.15 = 300.15 K
* Solve for n (number of moles):
* n = (PV) / (RT) = (1.12 atm * 0.0743 L) / (0.0821 L⋅atm/(mol⋅K) * 300.15 K) ≈ 0.0034 mol
* Calculate molar mass:
* Molar mass = mass / moles = 0.0934 g / 0.0034 mol ≈ 27.5 g/mol
3. Determine the molecular formula:
* Find the ratio of the molar mass to the empirical formula mass:
* Empirical formula mass of BH₃ = 10.81 g/mol + 3(1.01 g/mol) = 13.84 g/mol
* Ratio = 27.5 g/mol / 13.84 g/mol ≈ 2
* Multiply the subscripts in the empirical formula by the ratio:
* Molecular formula: (BH₃)₂ = B₂H₆
Therefore, the molecular formula of the gas compound is B₂H₆.