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  • Determine Molecular Formula of a Boron-Hydrogen Compound: A Step-by-Step Guide
    Here's how to determine the molecular formula of the gas compound:

    1. Find the empirical formula:

    * Assume a 100 g sample: This makes the percentages directly into grams.

    * Convert grams to moles:

    * Moles of Boron (B): 78.14 g / 10.81 g/mol (molar mass of B) = 7.23 mol

    * Moles of Hydrogen (H): 21.86 g / 1.01 g/mol (molar mass of H) = 21.64 mol

    * Find the simplest whole-number ratio: Divide both mole values by the smaller one (7.23 mol):

    * B: 7.23 mol / 7.23 mol = 1

    * H: 21.64 mol / 7.23 mol ≈ 3

    * Empirical formula: BH₃

    2. Determine the molar mass:

    * Use the ideal gas law (PV = nRT):

    * P = 1.12 atm

    * V = 74.3 mL = 0.0743 L

    * R = 0.0821 L⋅atm/(mol⋅K)

    * T = 27°C + 273.15 = 300.15 K

    * Solve for n (number of moles):

    * n = (PV) / (RT) = (1.12 atm * 0.0743 L) / (0.0821 L⋅atm/(mol⋅K) * 300.15 K) ≈ 0.0034 mol

    * Calculate molar mass:

    * Molar mass = mass / moles = 0.0934 g / 0.0034 mol ≈ 27.5 g/mol

    3. Determine the molecular formula:

    * Find the ratio of the molar mass to the empirical formula mass:

    * Empirical formula mass of BH₃ = 10.81 g/mol + 3(1.01 g/mol) = 13.84 g/mol

    * Ratio = 27.5 g/mol / 13.84 g/mol ≈ 2

    * Multiply the subscripts in the empirical formula by the ratio:

    * Molecular formula: (BH₃)₂ = B₂H₆

    Therefore, the molecular formula of the gas compound is B₂H₆.

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