What is electrolysis?
Electrolysis is the process of using an electric current to drive a non-spontaneous chemical reaction. In the case of water, electrolysis breaks down water (H₂O) into its component elements: hydrogen (H₂) and oxygen (O₂).
The setup:
1. Electrolytic Cell: This is a container containing the solution to be electrolyzed.
2. Electrodes: Two electrodes (usually made of inert metals like platinum or graphite) are submerged in the solution.
3. DC Power Source: A direct current (DC) power source provides the electrical energy for the reaction.
The process:
1. Connection: The electrodes are connected to the positive (+) and negative (-) terminals of the DC power source.
2. Electrolyte: The water solution contains a small amount of electrolyte (like sulfuric acid or sodium hydroxide) to improve conductivity.
3. Reaction at the Cathode (Negative Electrode): Hydrogen ions (H+) from the water are attracted to the negatively charged cathode. They gain electrons and form hydrogen gas (H₂), which is released as bubbles at the cathode.
4. Reaction at the Anode (Positive Electrode): Hydroxide ions (OH-) from the water are attracted to the positively charged anode. They lose electrons and form oxygen gas (O₂), which is released as bubbles at the anode.
Diagram:

Summary of the reactions:
* Cathode: 2H⁺ + 2e⁻ → H₂
* Anode: 4OH⁻ → 2H₂O + O₂ + 4e⁻
The overall reaction:
2H₂O → 2H₂ + O₂
Key points:
* Electrolysis of water requires a DC power source.
* The volume of hydrogen gas produced is twice the volume of oxygen gas.
* Electrolysis is a process used to produce pure hydrogen gas, which is used in fuel cells and other applications.
Note: This is a simplified explanation. The actual process is more complex and involves various factors like the concentration of the electrolyte, the electrode material, and the applied voltage.