Here's why:
* Potassium is in group 1 of the periodic table and has a +1 charge when it becomes an ion.
* Bromine is in group 17 of the periodic table and has a -1 charge when it becomes an ion.
To form a neutral compound, the charges must balance out. Therefore, one potassium ion (K+) combines with one bromide ion (Br-) to form potassium bromide (KBr).