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  • β-Naphthol and Sodium Hydroxide Reaction: Mechanism & Products
    The reaction of β-naphthol with sodium hydroxide is a classic example of an acid-base reaction leading to the formation of a phenolate salt.

    Here's a breakdown of the reaction:

    Reactants:

    * β-naphthol: A weakly acidic aromatic compound with a hydroxyl group (-OH) attached to the second carbon atom of the naphthalene ring.

    * Sodium hydroxide (NaOH): A strong base.

    Reaction:

    The hydroxide ion (OH-) from sodium hydroxide acts as a base, deprotonating the hydroxyl group of β-naphthol. This results in the formation of the β-naphtholate anion and water.

    Product:

    * Sodium β-naphtholate: This is the salt formed by the reaction. The sodium cation (Na+) from sodium hydroxide combines with the β-naphtholate anion.

    Chemical Equation:

    ```

    C10H7OH + NaOH → C10H7ONa + H2O

    ```

    Explanation:

    * The hydroxyl group (-OH) in β-naphthol is slightly acidic due to the electron-withdrawing effect of the aromatic ring.

    * The hydroxide ion (OH-) from NaOH is a strong base and readily removes the proton (H+) from the hydroxyl group of β-naphthol.

    * The resulting β-naphtholate anion is resonance stabilized, making the reaction favorable.

    Important Note:

    The reaction is reversible. Adding an acid to the solution will protonate the β-naphtholate anion, regenerating β-naphthol.

    Applications:

    The reaction between β-naphthol and sodium hydroxide has various applications, including:

    * Dye synthesis: β-naphtholate is an important intermediate in the synthesis of many azo dyes.

    * Antioxidant: β-naphthol and its derivatives are used as antioxidants in various materials.

    * Pharmaceuticals: Some β-naphthol derivatives have medicinal properties and are used in pharmaceuticals.

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