Here are the equations for the dissociation constants of carbonic acid:
1. First dissociation:
H₂CO₃(aq) ⇌ H⁺(aq) + HCO₃⁻(aq)
Ka1 = [H⁺][HCO₃⁻] / [H₂CO₃] = 4.3 × 10⁻⁷
2. Second dissociation:
HCO₃⁻(aq) ⇌ H⁺(aq) + CO₃²⁻(aq)
Ka2 = [H⁺][CO₃²⁻] / [HCO₃⁻] = 4.7 × 10⁻¹¹
Note: The values of Ka1 and Ka2 are given at 25°C.