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  • Oxidation of Ethanol with Potassium Dichromate: Products & Conditions
    The product of oxidation of ethanol with K₂Cr₂O₇ (potassium dichromate) depends on the reaction conditions, specifically the concentration of the oxidizing agent and the presence of a catalyst.

    Here are the possible outcomes:

    1. Primary Alcohol Oxidation:

    * Mild conditions (dilute K₂Cr₂O₇, acidic medium): Ethanol is oxidized to ethanal (acetaldehyde).

    CH₃CH₂OH + [O] → CH₃CHO + H₂O

    * Strong conditions (concentrated K₂Cr₂O₇, acidic medium): Ethanol is oxidized further to ethanoic acid (acetic acid).

    CH₃CHO + [O] → CH₃COOH

    2. Secondary Alcohol Oxidation:

    * If the reaction is carried out with a secondary alcohol, like propan-2-ol, the product will be a ketone (propanone/acetone) regardless of the concentration of the oxidizing agent.

    It's important to remember that K₂Cr₂O₇ acts as an oxidizing agent in the presence of an acid, typically sulfuric acid (H₂SO₄).

    Let me know if you have any more questions!

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