Understanding the Concepts
* Boiling Point Elevation: When a non-volatile solute (like adrenaline) is dissolved in a solvent (like CCl4), it raises the boiling point of the solution. This elevation is directly proportional to the molality of the solution.
* Molality: Molality (m) is defined as the moles of solute per kilogram of solvent.
* The Equation: The relationship between boiling point elevation (ΔTb), molality (m), and the molal boiling point elevation constant (Kb) is:
ΔTb = Kb * m
Steps
1. Find the Molal Boiling Point Elevation Constant (Kb) for CCl4: You'll need to look this up in a reference table. The Kb for CCl4 is approximately 5.02 °C/m.
2. Calculate the Molality (m):
* ΔTb = 0.49 °C
* Kb = 5.02 °C/m
* m = ΔTb / Kb = 0.49 °C / 5.02 °C/m = 0.0976 m
3. Calculate the Moles of Adrenaline:
* Mass of adrenaline = 0.64 g
* Mass of CCl4 = 36.0 g = 0.036 kg (convert grams to kilograms)
* Molality = 0.0976 mol/kg
* Moles of adrenaline = Molality * Mass of solvent = 0.0976 mol/kg * 0.036 kg = 0.00351 mol
4. Calculate the Molar Mass:
* Molar mass = Mass of adrenaline / Moles of adrenaline = 0.64 g / 0.00351 mol = 182.3 g/mol
Therefore, the approximate molar mass of adrenaline in this solution is 182.3 g/mol.
Important Note: This calculation assumes that adrenaline behaves ideally as a non-volatile solute in CCl4. In reality, there might be slight deviations from ideal behavior.