1. Write the unbalanced equation:
NO₂ + H₂O → HNO₃ + NO
2. Balance the nitrogen atoms:
There are two nitrogen atoms on the left side and two on the right side, so nitrogen is already balanced.
3. Balance the hydrogen atoms:
There are two hydrogen atoms on the left side and one on the right side. To balance, add a coefficient of 2 in front of HNO₃:
NO₂ + H₂O → 2HNO₃ + NO
4. Balance the oxygen atoms:
There are three oxygen atoms on the left side and six on the right side. To balance, add a coefficient of 3 in front of NO₂:
3NO₂ + H₂O → 2HNO₃ + NO
5. Final balanced equation:
3NO₂ + H₂O → 2HNO₃ + NO
Explanation:
This reaction demonstrates the disproportionation of nitrogen dioxide. Nitrogen in NO₂ is in an oxidation state of +4. In the products, nitrogen is in an oxidation state of +5 in HNO₃ and +2 in NO.