1. Identify the Reactants and Products:
* Reactant: Sulfate ion (SO₄²⁻)
* Product: Sulfite ion (SO₃²⁻)
2. Balance the Oxygen Atoms:
* Add one water molecule (H₂O) to the product side to balance the oxygen atoms:
SO₄²⁻ → SO₃²⁻ + H₂O
3. Balance the Hydrogen Atoms:
* Add two hydrogen ions (H⁺) to the reactant side:
SO₄²⁻ + 2H⁺ → SO₃²⁻ + H₂O
4. Balance the Charges:
* The charges on both sides are now balanced:
SO₄²⁻ + 2H⁺ + 2e⁻ → SO₃²⁻ + H₂O
The balanced half-reaction is:
SO₄²⁻ + 2H⁺ + 2e⁻ → SO₃²⁻ + H₂O