* Atomic Radius: The atomic radius refers to the distance from the nucleus to the outermost electron shell of an atom.
* Ionic Radius: The ionic radius refers to the distance from the nucleus to the outermost electron shell of an ion.
Chlorine Atom: A chlorine atom has 17 electrons and 17 protons. The outermost shell has 7 electrons.
Chloride Ion (Cl⁻): When a chlorine atom gains an electron to form a chloride ion, it now has 18 electrons and 17 protons. This extra electron goes into the outermost shell, making it more negatively charged and causing a greater repulsion between the electrons. This repulsion pushes the electron shells further away from the nucleus, resulting in a larger ionic radius compared to the atomic radius.
In summary:
* Cl atom: Smaller radius (due to fewer electrons and less repulsion)
* Cl⁻ ion: Larger radius (due to more electrons and greater repulsion)