Here's why:
* Kinetic Molecular Theory: The Kinetic Molecular Theory states that gas molecules are in constant random motion, and their average kinetic energy is directly proportional to the absolute temperature.
* Decreased Temperature, Decreased Kinetic Energy: When temperature decreases, the average kinetic energy of the gas molecules decreases. This means they move slower.
* Less Collisions: Slower molecules collide less frequently with the walls of the container.
* Reduced Pressure: Reduced collisions mean less pressure exerted on the container walls.
* Volume Contraction: To maintain a constant pressure, the volume of the gas must decrease to compensate for the reduced number of collisions.
This relationship between temperature and volume is summarized by Charles's Law:
V₁/T₁ = V₂/T₂
Where:
* V₁ is the initial volume
* T₁ is the initial temperature
* V₂ is the final volume
* T₂ is the final temperature
Important Note: This relationship holds true only if the pressure and amount of gas remain constant.