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  • NH₄NO₃ Decomposition: Is it a Disproportionation Reaction? | Chemistry Explained
    Yes, the reaction of ammonium nitrate (NH₄NO₃) to form nitrous oxide (N₂O) and water (H₂O) is a disproportionation reaction. Here's why:

    Disproportionation Reaction: A disproportionation reaction is a redox reaction where the same element undergoes both oxidation and reduction.

    Analyzing the reaction:

    * NH₄NO₃ → N₂O + 2H₂O

    1. Nitrogen in NH₄NO₃: Nitrogen has an oxidation state of -3 in ammonium (NH₄⁺) and +5 in nitrate (NO₃⁻).

    2. Nitrogen in N₂O: Nitrogen has an oxidation state of +1 in nitrous oxide (N₂O).

    3. Nitrogen in H₂O: Nitrogen is not present in water.

    Observation: In this reaction, nitrogen in the reactant (NH₄NO₃) is present in two different oxidation states (-3 and +5). In the product, nitrogen (N₂O) has an oxidation state of +1. This means:

    * Nitrogen in ammonium (NH₄⁺) is oxidized: From -3 to +1.

    * Nitrogen in nitrate (NO₃⁻) is reduced: From +5 to +1.

    Conclusion: Because the same element (nitrogen) undergoes both oxidation and reduction in the reaction, it is classified as a disproportionation reaction.

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