Volcanic Gases:
* Water Vapor (H₂O): A major component of the early atmosphere, leading to significant rainfall.
* Carbon Dioxide (CO₂): A greenhouse gas, contributing to the Earth's early heat.
* Nitrogen (N₂): While less abundant than today, it was still present.
* Methane (CH₄): A potent greenhouse gas, contributing to the Earth's early heat.
* Ammonia (NH₃): A key component of the early atmosphere, contributing to the formation of organic molecules.
* Hydrogen Sulfide (H₂S): A toxic gas, likely abundant in the early atmosphere.
Other Molecules:
* Hydrogen (H₂): A very light gas that could easily escape the atmosphere.
* Helium (He): Another light gas that could easily escape the atmosphere.
* Argon (Ar): A heavier gas that remained in the atmosphere.
Importantly, free oxygen (O₂) was almost entirely absent in the early Earth's atmosphere. It was only through the emergence of photosynthetic organisms (like cyanobacteria) that oxygen levels gradually rose.
Note: The exact composition of the early Earth's atmosphere is still a matter of debate among scientists. The above list represents the most commonly accepted constituents based on current evidence.