1. Assign known oxidation states:
* Ba (Barium): Group 2 elements have a +2 oxidation state.
* O (Oxygen): Oxygen typically has a -2 oxidation state (except in peroxides).
2. Set up an equation:
Let the oxidation state of Cl be "x". Since we have two ClO2 units, we multiply the oxidation state of Cl by 2.
The sum of the oxidation states in a neutral compound must equal zero:
(+2) + 2(x + 2(-2)) = 0
3. Solve for x:
* +2 + 2x - 8 = 0
* 2x - 6 = 0
* 2x = 6
* x = +3
Therefore, the oxidation state of Cl in Ba(ClO2)2 is +3.