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  • Work Done by a Gas: Calculating Work with Volume Change
    Here's how to understand the work done when the volume of a gas is doubled at atmospheric pressure:

    Understanding Work in Thermodynamics

    In thermodynamics, work (W) is done by a system when it expands against an external pressure. The formula for work is:

    * W = -PΔV

    Where:

    * W is the work done

    * P is the external pressure

    * ΔV is the change in volume

    Applying the Formula

    1. Atmospheric Pressure: We're given that the pressure is atmospheric pressure (P).

    2. Change in Volume: The volume doubles, meaning the change in volume (ΔV) is equal to the initial volume (V).

    Calculation

    * W = -P * (V)

    * W = -PV

    Conclusion

    The work done when the volume of a gas is doubled at atmospheric pressure is -PV, where P is the atmospheric pressure and V is the initial volume of the gas.

    Important Points:

    * Sign Convention: The negative sign indicates that work is done *by* the system (the gas) on its surroundings.

    * Isobaric Process: This scenario describes an isobaric process, meaning the pressure remains constant.

    * Ideal Gas Assumption: This calculation assumes the gas behaves ideally. Real gases may have deviations from this behavior.

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