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  • N₂O₃ Color Change with Temperature: Understanding the Equilibrium
    The pale blue liquid of N₂O₃ (dinitrogen trioxide) loses its colour on warming because of the equilibrium shift that occurs between its two components:

    * N₂O₃ (liquid) is a blue liquid at low temperatures, and it exists in equilibrium with its gaseous components:

    * NO₂ (nitrogen dioxide) is a brown gas.

    * NO (nitric oxide) is a colourless gas.

    The equilibrium reaction is:

    N₂O₃ (l) ⇌ NO₂ (g) + NO (g)

    Here's why the colour changes:

    * At low temperatures: The equilibrium favors the formation of N₂O₃, giving the liquid its blue color.

    * As temperature increases: The equilibrium shifts to the right, favoring the formation of NO₂ and NO.

    * NO₂ is brown: As more NO₂ is formed, the solution appears browner.

    * NO is colourless: The colourless NO gas contributes to the overall decrease in the blue colour.

    Therefore, the combination of decreasing blue colour (from less N₂O₃) and increasing brown colour (from more NO₂) results in a loss of the blue colour as the temperature increases.

    In summary, the colour change is due to the dynamic equilibrium shifting towards the gaseous components, NO₂ and NO, which are less coloured than N₂O₃.

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