Here's why:
* Benzene is the base name for the six-membered aromatic ring.
* When benzene acts as a substituent (attached to another molecule), it loses the "-ene" ending and becomes phenyl.
For example, if a benzene ring is attached to a methane molecule, the compound would be called methylbenzene or toluene. In this case, "phenyl" is used to describe the benzene ring as a substituent on the methane molecule.