1. Initially, a white precipitate of silver chloride forms due to the reaction between silver ions (Ag+) from the silver chloride solution and chloride ions (Cl-) from the aqueous ammonia.
2. As more ammonia is added, the silver chloride precipitate dissolves and forms a complex ion called diamminesilver(I) ion ([Ag(NH3)2]+). This complex ion is soluble in water.
3. The solution becomes colorless as the silver chloride precipitate dissolves.
The overall reaction can be represented as:
AgCl(s) + 2 NH3(aq) -> [Ag(NH3)2]+(aq) + Cl-(aq)
This reaction is reversible, and the addition of excess ammonia drives the equilibrium towards the formation of the complex ion.