In addition to absorbing water, copper sulphate can also react with other chemicals in the air. For example, it can react with carbon dioxide to form copper carbonate, which is a green solid. Copper carbonate is also a corrosive substance, and it can cause skin irritation and burns.
If copper sulphate is left in a dish for a long period of time, it will eventually evaporate and leave behind a solid residue. The residue is a mixture of copper sulphate and copper carbonate. The solid residue is not as corrosive as the liquid copper sulphate solution, but it can still cause skin irritation and burns.