In fractional distillation, the mixture of liquids is heated in a distillation column. The column is divided into several sections, each of which is maintained at a specific temperature. The vapours from the heated mixture rise up the column, and as they cool, they condense into liquids. The liquids collect in the different sections of the column, based on their boiling points.
The liquids with the lowest boiling points will condense at the top of the column, while the liquids with the highest boiling points will condense at the bottom. By carefully controlling the temperature of the column, it is possible to separate the mixture of liquids into its individual components.
Fractional distillation is a very efficient separation technique, and it can be used to separate mixtures of liquids that have very similar boiling points. It is also a versatile technique, and it can be used to separate a wide variety of mixtures.